oakchas said:
And, just for fun... Did you know that wooden boatrights will almost NEVER use SS fasteners below the waterline, or in a boat to be fiberglassed over?
Why? Because stainless steel requires the presence of air to remain "stainless."
True. But what you're actually referring to is called
"crevice corrosion" and that layer of air provides the insulation (if you will) that allows the SS to protect itself. 316 is the better SS series in that regard, but fugghedabout that for now.
Whenever SS is cut off from the oxide layer, it will corrode. Take a look of that photo of a SS bolt I pulled out of my transom swim platform that had only been installed for a few years! Not only is part of the body in the middle of the bolt "missing" but look where the threads to the left are deteriorating too.
FWIW ... here's some info I had posted on my Parker boat website regarding stainless steels that might help some:
Looking specifically at stainless steels, one can also quickly see why SS is great choice out of the water … but not the best choice for a mariner whenever it is fully immersed in water. And most SS hardware for the marine market is the 304 or equivalent series. (Note, SS can also be passivated, which adds protection, but I didn't want to bore you with too much details, but simply put ... passivation provides an extra measure of resistance and good corrosion resistance in stressful situations (salt spray, chloride contact, etc.) due to the chromium enrichment of the surface.).
* Galvanic corrosion is corrosion that naturally occurs between dissimilar metals. Put a SS fastener in a tin boat and the aluminum boat surrounding the SS fastener or hardware will be eaten away in time.
* Such corrosion is exacerbated in the presence of an electrolyte (water) and even worse, when coupled with a chloride (salt from saltwater). Now you know
?why? saltwater can be sooooooo corrosive. Further evidence of this that you may have seen for yourself is older aluminum spinning reels where the paint was flaking off around the SS screws. The aluminum housing under the paint was corroding within itself, and where the paint flaked off, you may have seen a white powered corrosion (salt).
* Stainless steel is not truly stainless. The high chromium and/or nickel content makes it stain‘less’, but no SS alloy is truly stainless.
* What causes SS to lose it’s protection? SS gets the layer of protection from the oxygen in the air, and/or it's passivated surface. Eliminate it - like immersing it in water, or allowing water to sit on the material, or completely encapsulating the SS fastener in an enclosed hole – and the SS will corrode. An example of this is when you see ‘rust’ forming on the tops of the SS screws used to hold SS cleats or SS rod holders onto the f’glass washboards.
* ‘Working’ SS (machined, punched, drilled, or welded) can remove the protective oxide layer. The heat or mechanical action can disrupt the atoms at the surface and remove the protective oxide layer, leaving the area worked pretty close to be plain carbon steel. This is why Lenco trim tabs can rust and fall off – happening to more than one I know of in its 1st year of use (as the rolled hinge area is also welded).
* SS is also prone to crevice corrosion when under heavy tensile loads. That is why those ‘cheap’ SS hose clamps look so darn rusty! It is under a load and the band was pierced by a heavy metal punch machine. I recommend full-band-type of hose clamps, known as AWAB brand clamps, for any critical below-the-waterline internal connections. I've seen SS bolts holding deck hardware on that were reduced to 1/2 their full diameter, in the middle of the bolt, because the SS was fully enclosed inside the boat structure, which cuts off the oxide protective layer.
* If you need to put SS through aluminum – insulate them. They make special lubricants or protective ‘goops’ for this (Tef-Gel is but one brand), but I use adhesive-line heatshrink on the fastener body and thick nylon washers under the bolt head and nylok nuts.